basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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Cell constant is defined as the conductivity of the cell: The value is 0. In other words, it is defined as the reciprocal of the resistance.

In another case, the titration will form two precipitates. Unsourced material may be challenged and removed.

Concentration of the sample solution: The excess addition of the NH 4 OH does not show the change in the conductivity. The following are the different bridges used for the measurement of the conductance: What are the different types of applications of conductometry? It consists of a meter bridge wire AB with a fixed resistance R princople both the ends. By using this site, you agree to principlr Terms of Use and Privacy Policy.


Conductometry – Wikipedia

Retrieved from ” https: In other projects Wikimedia Commons. Then the cell is connected to the resistor box R and the condkctometry current is passed through the cell with the help of induction coil. The basicity is defined as the number of carboxylic acid groups attached to the molecules. For example, titrations of the strong acid such as HCL with the weak base such as the ammonium hydroxide.

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Conductometry was further improved with the development of the glass electrode, which began in The conductance of the sample solution is measured by the resistance measurement by the Wheatstone bridge.

Because the high concentrations are not measured by the conductometric titrations. In Folin and Flanders titrated the acidic substances by using the non-aqueous solvents such as benzene, chloroform and chloroform-methanol mixture. In this method, the conductance of the hydrogen ions and hydroxyl ions are compared with the conductivity of the sample solution.


The temperature is maintained constant with the help of the thermostat. After the equivalence point is achieved the conductivity increases rapidly due to the excess OH- ions. This type cell is mainly used for the measurement of the low conductance.


In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titrationwhile the term conductimetry is used to describe non-titrative applications. Used in the determination of the ionic product of the water. These conductivity cells are made up of glass.

Strong electrolytes completely dissociate into ions and have high conductance. The conductivity is inversely proportional to the size of the ions. That is mainly of the conductometfy of ions present in the solution. Articles needing additional references from January All articles cpnductometry additional references. This page was last edited on 16 Decemberat The sample solution is placed in the conductivity cell at constant temperature.

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Nehmat Sandhu 10 November at This method is mainly used for the determination of the physico-chemical properties of the compounds.